|
|
3-[(2S,5R)-5-hydroxy-7-oxabicyclo[4.1.0]heptan-2-yl]-2-oxopropanoate + NADP+ <=> 3-[(2Z,5R)-5-hydroxy-7-oxabicyclo[4.1.0]heptan-2-ylidene]-2-oxopropanoate + NADPH + H+
|
1.3.1.aa
|
–
|
|
MetaCyc:
RXN-16265
|
|
|
|
3-[(2S,5R)-5-hydroxy-7-oxabicyclo[4.1.0]heptan-2-yl]-2-oxopropanoate + L-phenylalanine <=> L-dihydroanticapsin + phenylpyruvate
|
2.6.1
|
–
|
|
KEGG:
R11068
MetaCyc:
RXN-16297
|
|
|
|
3-[(2E,5R)-5-hydroxy-7-oxabicyclo[4.1.0]heptan-2-ylidene]-2-oxopropanoate <=> 3-[(2Z,5R)-5-hydroxy-7-oxabicyclo[4.1.0]heptan-2-ylidene]-2-oxopropanoate
|
5.3.3.19
3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate isomerase
|
–
|
|
MetaCyc:
RXN-16300
|
|
|
|
chorismate <=> prephenate
|
5.4.99.5
chorismate mutase
|
–
|
|
BRENDA:
BR252
KEGG:
R01715
MetaCyc:
CHORISMATEMUT-RXN
SABIO-RK:
1827
|
|
|
|
3-[(2S,5R)-5-hydroxy-7-oxabicyclo[4.1.0]heptan-2-yl]-2-oxopropanoate + NADP+ <=> 3-[(2E,5R)-5-hydroxy-7-oxabicyclo[4.1.0]heptan-2-ylidene]-2-oxopropanoate + NADPH + H+
|
1.3.1.aa
|
–
|
|
MetaCyc:
RXN-16298
|
|
|
|
3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate <=> (3E)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate
|
5.3.3.19
3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate isomerase
|
–
|
|
BRENDA:
BR51252
KEGG:
R11065
MetaCyc:
RXN-16264
|
|
|
|
(3E)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate + O2 + reduced_acceptor <=> 3-[(2E,5R)-5-hydroxy-7-oxabicyclo[4.1.0]heptan-2-ylidene]-2-oxopropanoate + H2O + acceptor
|
1.14.13
|
–
|
|
MetaCyc:
RXN-16299
|
|
|
|
L-dihydroanticapsin + NAD+ <=> anticapsin + NADH + H+
|
1.1.1.385
dihydroanticapsin dehydrogenase
|
–
|
|
BRENDA:
BR51207
KEGG:
R10917
MetaCyc:
RXN-16285
|
|
|
|
H+ + prephenate <=> 3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate + CO2
|
4.1.1.100
prephenate decarboxylase
|
–
|
|
BRENDA:
BR51243
KEGG:
R10934
MetaCyc:
RXN-16263
|
|
|
|
ATP + L-alanine + anticapsin <=> ADP + phosphate + L-alanyl-L-anticapsin + H+
|
6.3.2.49
L-alanine---L-anticapsin ligase
|
–
|
|
BRENDA:
BR48759
KEGG:
R11064
MetaCyc:
RXN-16296
|
|